منابع مشابه
Raman optical activity of tetra-alanine in the poly(l-proline) II type peptide conformation.
The poly(l-proline) II (PPII) helix is considered to be a major conformation in disordered polypeptides and unfolded proteins in aqueous solution. The PPII conformation can be identified by using Raman optical activity (ROA), which measures the different intensities of right- and left-circularly polarized Raman scattered light from chiral molecules and provides information on stereochemistry as...
متن کاملDependence of the AmII'p proline Raman band on peptide conformation.
We utilized UV resonance Raman (UVRR) measurements and density functional theory (DFT) calculations to relate the AmII'p frequency to the psi angle. The AmII'p frequency shifts by approximately 25 cm(-1) as the psi angle is varied over allowed angles of the Pro peptide bond. The AmII'p frequency does not show any significant dependence on the phi dihedral angle. The conformation sensitivity of ...
متن کاملGas-phase conformation-specific photofragmentation of proline-containing peptide ions.
Singly-protonated proline-containing peptides with N-terminal arginine are photodissociated with vacuum ultraviolet (VUV) light in an ESI linear ion trap/orthogonal-TOF (LIT/o-TOF). When proline is the nth residue from the N-terminus, unusual b(n) + 2 and a(n) + 2 ions are observed. Their formation is explained by homolytic cleavage of the C(alpha)-C bond in conjunction with a rearrangement of ...
متن کاملA new method for isolation of hydroxy-L-proline and L-proline from gelatin.
Several investigators have reported that commercial L-proline is contaminated with small amounts of hydroxy-n-proline (l-3). During the course of investigations in this laboratory all of five commercial samples proved to contain up to 3.5 per cent hydroxyproline when tested by the method of Neuman and Logan (1). The preparation of n-proline from gelatin by the formation of complex salts is tedi...
متن کاملRedetermination of poly[μ-chlorido-heptachlorido-μ3-l-proline-μ2-l-proline-tetramercury(II)]
The asymmetric unit of the title compound, [Hg(4)Cl(8)(C(5)H(9)NO(2))(2)](n), consists of four HgCl(2) units and two L-proline ligands in the zwitterionic form. In each HgCl(2) unit, the Hg(II) ion is strongly bonded to two Cl atoms, and the Hg(II) ions in two of the HgCl(2) units are chelated by O atoms of two l-proline ligands, with one strong and one weak Hg-O bond. In the crystal structure,...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1973
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.46.3894